195. polarization effects on the interfacial conductivity in the lao/sto heterostructure: first-principles study
Name: Maziar Alexander Behtash
Grad Year: 2018
We studied the influence of uniaxial  strain on the electron transport properties of two-dimensional electron gas (2DEG) at the n-type interface of the LaAlO3/SrTiO3(LAO/STO) heterostructure (HS)-based slab system from the perspective of polarization effects via first-principles density functional theory calculations. We first analyzed the unstrained system, and found that the induced polarization toward the vacuum in the LAO film leads to a small charge carrier density on the order of 1E13 [cm^-2] (less than the theoretical value of 3.3E14 [cm^-2] from the superlattice-model-based polar catastrophe mechanism), which is in excellent agreement with the experimental values for oxygen-annealed LAO/STO HS samples. Upon applying a  tensile strain on the STO substrate, we found a significant reduction of the induced polarization in the LAO film. This reduction weakens the driving force against charge transfer from LAO to STO, causing an increase in the interfacial charge carrier density. The uniaxial strain also leads to a decrease of the effective mass of interfacial mobile electrons, resulting in a higher electron mobility. These findings suggest that applying a uniaxial  tensile strain on the STO substrate can significantly enhance the interfacial conductivity of the LAO/STO HS system, which gives a comprehensive explanation for experimental observations. In contrast, compressively strained LAO/STO systems show stronger LAO film polarization than the unstrained system, which reduces the interfacial charge carrier density and increases the electron effective mass, thus suppressing the interfacial conductivity.
Industry Application Area(s)
Electronics/Photonics | Energy/Clean technology | Semiconductor